1
MSc in mechanical engineering, Imam Hossein Comprehensive University
2
Academic Sttaf, Imam Hossein Comprehensive University
10.22059/ses.2024.376446.1066
Abstract
Al-H2O2 battery is a primary flow battery used in underwater systems. These batteries are of interest for air-independent power sources in underwater vehicles. Currently, with the development of the use of light and smart underwater vehicles and the need to increase the durability of the submarine, special attention has been paid to these batteries. In this study, the effect of the separator membrance on the Al-H2O2 battery on the hydrodynamic and thermal performance of this battery has been investigated numerically and experimentally. The use of the separator is to prevent short circuit in the battery, to control the corrosion rate of aluminum and also to improve the performance of the battery. Comsol software has been used to simulate the hydrodynamic and thermoelectrochemical performance of the Al-H2O2 battery. Also, k-w turbulence model is used to solve momentum conservation equations. In order to validate the numerical results, experimental tests were performed. The numerical results were in good agreement with the experimental results. By increasing the current to two times in the case of using the separator, the average voltage has changed over time from 1.07 V in the case without the separator to 0.97 V in the case with the separator. The voltage change was about 10%, while the current increased by 100%. This indicates improved battery performance and higher power draw when using the separator. Experimental and numerical results showed that the use of a separator in the Al-H2O2 battery improves the performance of the battery due to the prevention of direct contact between the H2O2 and the aluminum surface.
Palanisamy S, Shanmugasundaram L, Chenniappan S. Energy Storage Systems for Smart Power Systems. Artif Intell Smart Power Syst. 2023;99–114.
Feng Y, Wang R chu, Peng C qun. Influence of aging treatments on microstructure and electrochemical properties in Mg–8.8 Hg–8Ga (wt%) alloy. Intermetallics. 2013;33:120–5.
Wilcock WSD, Kauffman PC. Development of a seawater battery for deep-water applications. J Power Sources. 1997;66(1–2):71–5.
Hasvold Ø, Lian T, Haakaas E, Størkersen N, Perelman O, Cordier S. CLIPPER: a long-range, autonomous underwater vehicle using magnesium fuel and oxygen from the sea. J Power Sources. 2004;136(2):232–9.
Liu Q, Yan Z, Wang E, Wang S, Sun G. A high-specific-energy magnesium/water battery for full-depth ocean application. Int J Hydrogen Energy. 2017;42(36):23045–53.
Zhang J, Liu H, Huang J, Liu Y, Fang H, Zhang Q, et al. In situ synthesis of AgCl@ Ag plates as binder-free cathodes in a magnesium seawater-activated battery. J Electrochem Soc. 2022;169(5):50502.
Deng S hao, Yuan L jun, Chen Y bo, Wang B. Electrochemical synthesis and performance of polyaniline/MnO2/graphene oxide composites cathode for seawater battery. Appl Surf Sci. 2022;581:152261.
Lv Y, Xu Y, Cao D. The electrochemical behaviors of mg, mg–Li–Al–Ce and mg–Li–Al–Ce–Y in sodium chloride solution. J Power Sources. 2011;196(20):8809–14.
Lee B, Paek E, Mitlin D, Lee SW. Sodium metal anodes: emerging solutions to dendrite growth. Chem Rev. 2019;119(8):5416–60.
Lin D, Liu Y, Cui Y. Reviving the lithium metal anode for high-energy batteries. Nat Nanotechnol. 2017;12(3):194–206.
Qin R, Wang Y, Yao L, Yang L, Zhao Q, Ding S, et al. Progress in interface structure and modification of zinc anode for aqueous batteries. Nano Energy. 2022;98:107333.
Vlaskin MS, Shkolnikov EI, Bersh A V, Zhuk AZ, Lisicyn A V, Sorokovikov AI, et al. An experimental aluminum-fueled power plant. J Power Sources. 2011;196(20):8828–35.
Li Q, Bjerrum NJ. Aluminum as anode for energy storage and conversion: a review. J Power Sources. 2002;110(1):1–10.
Yang S, Knickle H. Design and analysis of aluminum/air battery system for electric vehicles. J Power Sources. 2002;112(1):162–73.
Chen J, Xu W, Wang X, Yang S, Xiong C. Progress and Applications of Seawater-Activated Batteries. Sustainability. 2023;15(2):1635.
Kim Y, Lee W geun. Primary Seawater Batteries. In: Seawater Batteries: Principles, Materials and Technology. Springer; 2022. p. 37–90.
Hasvold O, Johansen KH. The alkaline aluminium hydrogen peroxide semi-fuel cell for the HUGIN 3000 autonomous underwater vehicle. In: Proceedings of the 2002 Workshop on Autonomous Underwater Vehicles, 2002. IEEE; 2002. p. 89–94.
Kongsberg Maritime AS. Autonomous Underwater Vehicle–AUV: The HUGIN Family. 2009.
Rao BML, Hoge WH, Zakrzewski J, Shah S, Hamlen RP, Halliop W. Aluminum-sea water battery for undersea vehicle. In: Proceedings of the 6th International Symposium on Unmanned Untethered Submersible Technology,. IEEE; 1989. p. 100–8.
Marsh CL, Licht SL, Matthews DE. Dual flow aluminum hydrogen peroxide battery. Google Patents; 1995.
Shin DM, Son H, Park KU, Choi J, Suk J, Kang ES, et al. Al2O3 ceramic/nanocellulose-coated non-woven separator for lithium-metal batteries. Coatings. 2023;13(5):916.
Cheon J, Park SH, Kim Y, Yim T. Aluminum oxide and ethylene bis (diphenylphosphine)‐incorporated poly (imide) separators for lithium‐ion batteries. Bull Korean Chem Soc. 2022;43(9):1103–10.
Ding L, Li D, Du F, Zhang D, Zhang S, Xu R, et al. Fabrication of Nano-Al2O3 in-situ coating lithium-ion battery separator based on synchronous biaxial stretching mechanism of β-crystal polypropylene. Ind Eng Chem Res. 2022;61(30):11034–45.
Yang LY, Cao JH, Liang WH, Wang YK, Wu DY. Effects of the separator MOF-Al2O3 coating on battery rate performance and solid–electrolyte interphase formation. ACS Appl Mater Interfaces. 2022;14(11):13722–32.
Klein S, Wrogemann JM, van Wickeren S, Harte P, Bärmann P, Heidrich B, et al. Understanding the Role of Commercial Separators and Their Reactivity toward LiPF6 on the Failure Mechanism of High‐Voltage NCM523|| Graphite Lithium Ion Cells. Adv Energy Mater. 2022;12(2):2102599.
Rajagopalan Kannan DR, Terala PK, Moss PL, Weatherspoon MH. Analysis of the separator thickness and porosity on the performance of lithium-ion batteries. Int J Electrochem. 2018;2018.
Lei T, Tian YM, Wang GL, Yin JL, Gao YY, Wen Q, et al. An alkaline Al–H2O2 semi‐fuel cell based on a nickel foam supported Co3O4 nanowire arrays cathode. Fuel Cells. 2011;11(3):431–5.
Pazhan, A., & Nahidi, S. (2024). Effect On Improving Hydrodynamic And Thermal Performance Of Primary Al-H2O2 Flow Battery By Adding Separator Membrane Among Anode And Cathode Electrodes Based On Experimental And Numerical Studies. Journal of sustainable Energy Systems, 3(2), 113-138. doi: 10.22059/ses.2024.376446.1066
MLA
Alireza Pazhan; Saeed Nahidi. "Effect On Improving Hydrodynamic And Thermal Performance Of Primary Al-H2O2 Flow Battery By Adding Separator Membrane Among Anode And Cathode Electrodes Based On Experimental And Numerical Studies", Journal of sustainable Energy Systems, 3, 2, 2024, 113-138. doi: 10.22059/ses.2024.376446.1066
HARVARD
Pazhan, A., Nahidi, S. (2024). 'Effect On Improving Hydrodynamic And Thermal Performance Of Primary Al-H2O2 Flow Battery By Adding Separator Membrane Among Anode And Cathode Electrodes Based On Experimental And Numerical Studies', Journal of sustainable Energy Systems, 3(2), pp. 113-138. doi: 10.22059/ses.2024.376446.1066
VANCOUVER
Pazhan, A., Nahidi, S. Effect On Improving Hydrodynamic And Thermal Performance Of Primary Al-H2O2 Flow Battery By Adding Separator Membrane Among Anode And Cathode Electrodes Based On Experimental And Numerical Studies. Journal of sustainable Energy Systems, 2024; 3(2): 113-138. doi: 10.22059/ses.2024.376446.1066